One difficulty with this mechanism is the geometric constraint of the C=C bonds in the alkoxyl radical intermediate which clearly would strongly disfavor cyclization. A more reasonable scenario ...

Nature Chemistry: “Metalloradical approach for concurrent control in intermolecular radical allylic C−H amination" DOI: 10.1038/s41557-022-01119-4 ...

In recent research 4 we have observed a case of true electromerism in a pair of organic radical cations containing two allylic moieties. The two electromers distinguish themselves by the nature of ...

the copper-catalyzed radical-mediated sp 3 C-H oxidation has emerged as an important method for the selective oxidation of allylic, propargylic, and other sp 3 C-H bonds. Despite progress in ...